A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

Application of pyrolysis-GC/MS for rapid assessment of organic contamination in sediments from Barcelona harbor     

Michael A. Kruge  Albert Permanyer   《Organic Geochemistry》2004,35(11-12):1395

Pyrolysis-GC/MS is advantageous as a tool for rapid sediment contamination assessment because of the small sample size required, minimal sample preparation and its ability to detect a wide variety of organic pollutants as well as naturally-occurring biological materials. Py-GC/MS was applied, together with determination of organic carbon, and major and minor element concentrations, to evaluate potentially contaminated sediments in the port of Barcelona (Spain) and the adjacent Llobregat River delta. Detected contaminant markers, most evident in the Old Port (Port Vell) area, included hopanes and alkylated PAHs (petroleum), sterenes (sewage), C₁₆–C₁₉ phenylalkanes (detergents) and parent PAHs (combusted fuels).  相似文献   

The Elusive AD 1826 Tsunami, South Westland, New Zealand   总被引：1，自引：0，他引：1  

James R. Gofr Andrew Wells  Catherine Chagu‐Goff  Scott L. Nichol  Robert J.N. Devoy 《New Zealand geographer》2004,60(2):28-39

In AD 1826 sealers reported earthquake and tsunami activity in Fiordland, although, contemporary or near‐contemporary accounts of tsunami inundation at the time are elusive. A detailed analysis of recent sediments from Okarito Lagoon builds on contextual evidence provided by earlier research concerning past tsunami inundation. Sedimentological, geochemical, micropalaeontological and geochronological data are used to determine palaeoenvironments before, during and after what was most probably tsunami inundation in AD 1826. The most compelling chronological control is provided fry a young cohort of trees growing on a raised shoreline bench stranded fry a drop in the lagoon water level following tsunami inundation.  相似文献   

MTBE in Drinking Water Production – Occurrence and Efficiency of Treatment Technologies     

Christine Baus  HsuWen Hung  Frank Sacher  Michael Fleig  Heinz‐Jürgen Brauch 《洁净——土壤、空气、水》2005,33(2):118-132

In Germany, the gasoline additive methyl tert‐butyl ether (MTBE) is almost constantly detected in measurable concentrations in surface waters and is not significantly removed during riverbank filtration. The removal of MTBE from water has been the focus of many studies that mostly were performed at high concentration levels and centred in understanding the mechanisms of elimination. In order to assess the performance of conventional and advanced water treatment technologies for MTBE removal in the low concentration range further studies were undertaken. Laboratory experiments included aeration, granulated activated carbon (GAC) adsorption, ozonation and advanced oxidation processes (AOP). The results show that the removal of MTBE by conventional technologies is not easily achieved. MTBE is only removed by aeration at high expense. Ozonation at neutral pH values did not prove to be effective in eliminating MTBE at all. The use of ozone/H₂O₂ (AOP) may lead to a partly elimination of MTBE. However, the ozone/H₂O₂ concentrations required for a complete removal of MTBE from natural waters is much higher than the ozone levels applied nowadays in waterworks. MTBE is only poorly adsorbed on activated carbon, thus GAC filtration is not efficient in eliminating MTBE. A comparison with real‐life data from German waterworks reveals that if MTBE is detected in the raw water it is most often found in the corresponding drinking water as well due to the poor removal efficiency of conventional treatment steps.  相似文献   

Short‐term intertidal bar mobility on a ridge‐and‐runnel beach,Merlimont, northern France     

E. J. Anthony  F. Levoy  D. Monfort  C. Degryse‐Kulkarni 《地球表面变化过程与地形》2005,30(1):81-93

Digital elevation models and topographic pro?les of a beach with intertidal bar and trough (ridge‐and‐runnel) morphology in Merlimont, northern France, were analysed in order to assess patterns of cross‐shore and longshore intertidal bar mobility. The beach exhibited a pronounced dual bar–trough system that showed cross‐shore stationarity. The bars and troughs were, however, characterized by signi?cant longshore advection of sand under the in?uence of suspension by waves and transport by strong tide‐ and wind‐driven longshore currents. Pro?le changes were due in part to the longshore migration of medium‐sized bedforms. The potential for cross‐shore bar migration appears to be mitigated by the large size of the two bars relative to incident wave energy, which is modulated by high vertical tidal excursion rates on this beach due to the large tidal range (mean spring tidal range = 8·3 m). Cross‐shore bar migration is also probably hindered by the well‐entrenched troughs which are maintained by channelled high‐energy intertidal ?ows generated by swash bores and by tidal discharge and drainage. The longshore migration of intertidal bars affecting Merlimont beach is embedded in a regional coastal sand transport pathway involving tidal and wind‐forced northward residual ?ows affecting the rectilinear northern French coast in the eastern English Channel. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

An automated salt‐tracing gauge for flow‐velocity measurement     

Olivier Planchon  Norbert Silvera  Raphael Gimenez  David Favis‐Mortlock  John Wainwright  Yves Le Bissonnais  Gerard Govers 《地球表面变化过程与地形》2005,30(7):833-844

This article introduces the SVG (salt‐velocity gauge), a novel automated technique for measuring flow velocity by means of salt tracing. SVG allows a high measuring rate (up to one every 2 seconds), short control section length (down to 10 cm), high accuracy (+[sol ]?1·5 cm s^?1), and unbiased calculation of the mean velocity in experimental conditions with turbulent, supercritical flow. A few cubic centimetres of saturated salt solution (NaCl) are injected into the flow at regular time intervals using a programmable solenoid valve. The tracer successively passes two conductivity probes placed a short distance downstream. The transformation of the signal between the two probes is modelled as a one‐dimensional diffusion wave equation. Model calibration gives an estimation of the mean velocity and the diffusion for each salt plume. Two implementations of the SVG technique are described. The first was an outdoors simulated rainfall experiment in Senegal (conductivity probes at 40 cm apart, 8 Hz measurement rate, salt injections at 10 second intervals). Mean velocity was estimated to range between 0·1 and 0·3 m s^?1. The second was a laboratory‐based flume experiment (conductivity probes at 10 cm apart, 32 Hz, salt injections at 2 second intervals). Another SVG with probes at 34 cm apart was used for comparison. An acoustic Doppler velocimeter (ADV) was also used to give an independent assessment of velocity. Using the 10 cm salt gauge, estimated mean velocity ranged from 0·6 to 0·9 m s^?1 with a standard deviation of 1·5 cm s^?1. Comparisons between ADV, 10 cm SVG and 34 cm SVG were consistent and demonstrated that the salt‐tracing results were unbiased and independent of distance between probes. Most peaks were modelled with r² > 90 per cent. The SVG technology offers an alternative to the dye‐tracing technique, which has been severely criticized in the literature because of the wide interval of recommended values for the correction factor α to be applied to the timings. This article demonstrates that a fixed value of α is inappropriate, since the correction factor varies with velocity, diffusion and the length of the control section. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Probabilistic approach for active control of structures: experimental verification     

Jae‐Seung Hwang  Kyung‐Won Min  Sang‐Hyun Lee  Hongjin Kim 《地震工程与结构动力学》2005,34(3):207-225

In our previous study (Earthquake Engineering and Structural Dynamics 2003; 32 :2301), we have developed a probabilistic algorithm for active control of structures. In the probabilistic control algorithm, the control force is determined by the probability that the structural energy exceeds a specified target critical energy, and the direction of a control force is determined by the Lyapunov controller design method. In this paper, an experimental verification of the proposed probabilistic control algorithm is presented. A three‐story test structure equipped with an active mass driver (AMD) has been used. The effectiveness of the control algorithm has been examined by exciting the test structure using a sinusoidal signal, a scaled El Centro earthquake and a broadband Gaussian white noise; and, especially, experiments on control have been performed under different conditions to that of system identification in order to prove the stability and robustness of the proposed control algorithm. The experimental results indicate that the probabilistic control algorithm can achieve a significant response reduction under various types of ground excitations even when the modeling error exists. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Interannual Variability in Pollen Dispersal and Deposition on the Tropical Quelccaya Ice Cap*     

Carl A. Reese  Kam‐biu Liu 《The Professional geographer》2005,57(2):185-197

Pollen collected from snow samples on the Quelccaya Ice Cap in 2000 and 2001 reveals significant interannual variability in pollen assemblage, concentration, and provenance. Samples from 2000, a La Niña year, contain high pollen concentrations and resemble samples from the Andean forests (Yungas) to the east. Samples from 2001, an El Niño year, contain fewer pollen and resemble those from the Altiplano. We suggest that varying wind patterns under different El Niño/Southern Oscillation (ENSO) conditions may affect the processes of pollen transport over the Altiplano and on the ice cap, although confounding variables such as flowering phenology and sublimation should also be considered  相似文献   

Effect of suction on the mechanical behaviour of iron ore rock   总被引：1，自引：0，他引：1  

Dragan Grgic  Richard Giot  Franoise Homand  Albert Giraud 《国际地质力学数值与分析法杂志》2005,29(8):789-827

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Analysis of rock structure stability in coal mines   总被引：1，自引：0，他引：1  

Yi‐Shan Pan  Zhong‐Hua Li 《国际地质力学数值与分析法杂志》2005,29(10):1045-1063

In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献